In a medium bowl, combine the orange slices, chopped pear, chopped apples, bourbon, brown sugar and apple pie spice. Put into a sealable bag inside a bowl and store in the refrigerator. Give at least an hour for the fruit to soak up the Bourbon.
Once the fruit has soaked, in a large pitcher, combine white wine and apple cider. Add the Bourbon fruit to the wine and apple cider mixture. Serve over ice.
To add a sugar rim to each glass, combine white sugar and apple pie spice in a small bowl and then put on a small plate. On another plate, put a ¼ cup of water. Dip the top of the glass into the water then the sugar.